Bulk polymerization of cholesteryl acrylate
نویسندگان
چکیده
منابع مشابه
Insertion polymerization of acrylate.
Multiple insertions of acrylate in copolymerization with ethylene, and an insertion homo-oligomerization of methyl acrylate were observed for the first time. Key to these findings, and to mechanistic insights reported, are labile-substituted complexes as catalyst precursors.
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The proton spin-spin relaxation time (T2) during the bulk polymerization of methyl acrylate was measured as a function of the reaction time at various temperatures. Three kinds of T2 (T2L (long), T2S (short) and T2M (intermediate)) were obtained as the polymerization proceeded. The fraction of T2S (FS) increased sigmoidally at a certain reaction time, while that of T2L (FL) decreased reciprocal...
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In previous papers (1,2) the thermotropic properties and the kinetics of the bulk polymerization of the mesomorphic monomer cholesteryl acrylate have been described. In addition to cholesteryl acrylate, the methacrylate was prepared, as well as the respective acrylic methacrylic acid ester of cholestanol. We now wish to report the properties of these monomeric esters and the results of their po...
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Acrylate–alkyd hybrid latex via miniemulsion polymerizations show promise as water-borne coating systems. However, poor homogeneity of the particles caused by the immiscibility of the alkyd in polyacrylate limits monomer conversion and film formation. To resolve this problem, the hybrid miniemulsion polymerization of acrylate in the presence of linoleic acid and sunflower seed oil was carried o...
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Cloisite Na+was used as a solid surfactant (stabilizer) in Pickering emulsion polymerization of styrene-co-butyl acrylate in presence of oil soluble initiator, azobisisobutyronitrile (AIBN) and water soluble initiator, potassium persulfate (KPS). Fourier transform infrared (FTIR) spectrum approved the corporation of Cloisite Na+ layers within the polymer matrix. Effect of clay content was a...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part B: Polymer Letters
سال: 1970
ISSN: 0449-2986,1542-6254
DOI: 10.1002/pol.1970.110081110